MOUNTAINS 2020

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MOUNTAIN
RESEARCH
CENTER

O Norte Somos Nós

CIMO is the winner of the "O Norte Somos Nós" Awards in
the category of Research. See video HERE

MOUNTAIN
RESEARCH
CENTER

See a short video
about us

MOUNTAIN
RESEARCH
CENTER

Polytechnic Institute
of Bragança

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FROM NATURE TO PRODUCTS, TOWARDS SUSTAINABILITY.

Simão Pedro de Almeida Pinho

Coordinator Professor
Group: Sustainable Processes and Products
Phone: 273303086
E-mail: spinho@ipb.pt
ORCID: 0000-0002-9211-857X
Scopus Author ID: 7003570175

Career

  • Since 1995: lecturer at the Instituto Politécnico de Bragança (IPB), Bragança, Portugal

Roles

  • Since 1995: Coordinator of the Chemical and Biological Technology Department, President of the Assembly of Representatives and Vice President of the Scientific Council at the School of Technology and Management

Qualifications

  • 2000 - Ph.D. in Chemical Engineering at the Faculty of Engineering of the University of Porto (FEUP) , Porto, Portugal
  • 1992 - Chemical Engineering at the Faculty of Engineering of the University of Porto (FEUP) , Porto, Portugal

Interests

  • Applied Thermodynamics
  • Separation Processes and Process Simulation
  • Phase Equilibria and Thermo-Physical Properties
  • Electrolytes, Biomolecules, Terpenoids, Ionic Liquids, Deep Eutectic Solvents

Projects:

AllNat - Using natural deep eutectic solvents for the extraction of bioactive compounds from plant material
Funding body: 02/SAIC/2017
Reference: POCI-01-0145-FEDER-030463
Principal Investigator:Olga Ferreira
Start: 2018-06-01
End: 2021-05-31
BIOBLOCKS - Design of bio-based products as precursors for the bio-industry of chemical synthesis and biomaterials
Funding body: QREN
Reference: SI IDT - 33969/2012 F2
Principal Investigator:Maria Filomena Barreiro
Start: 2013-07-01
End: 2015-12-31
- Kinetic Modeling of the Molecular Architecture of Polymer Networks Formed in the Radical Cross-Linking Copolymerization of Acrylic/Trivinyl Monomers
Funding body: Research Directly Contract with Industry: BASF
Reference:
Principal Investigator:Rolando Dias
Start: 2008-01-09
End: 2011-08-31

Total results: 90
1
Vilas-Boas S.M.,Alves R.S.,Brandão P.,Campos L.M.A.,Coutinho J.A.P.,Pinho S.P.,Ferreira O.
Solid-liquid phase equilibrium of trans-cinnamic acid, p-coumaric acid and ferulic acid in water and organic solvents: Experimental and modelling studies
Fluid Phase Equilibria, 521, , 2020

2
Abranches D.O.,Silva L.P.,Martins M.A.R.,Pinho S.P.,Coutinho J.A.P.
Understanding the Formation of Deep Eutectic Solvents: Betaine as a Universal Hydrogen Bond Acceptor
ChemSusChem, 13, 4916-4921, 2020

3
Martins M.A.R.,Sharma G.,Pinho S.P.,Gardas R.L.,Coutinho J.A.P.,Carvalho P.J.
Selection and characterization of non-ideal ionic liquids mixtures to be used in CO2 capture
Fluid Phase Equilibria, 518, , 2020

4
Pérez-Sánchez G.,Santos Y.S.,Ferreira O.,Coutinho J.A.P.,Gomes J.R.B.,Pinho S.P.
The cation effect on the solubility of glycylglycine and N-acetylglycine in aqueous solution: Experimental and molecular dynamics studies
Journal of Molecular Liquids, 310, , 2020

5
Abranches D.O.,Benfica J.,Soares B.P.,Leal-Duaso A.,Sintra T.E.,Pires E.,Pinho S.P.,Shimizu S.,Coutinho J.A.P.
Unveiling the mechanism of hydrotropy: Evidence for water-mediated aggregation of hydrotropes around the solute
Chemical Communications, 56, 7143-7146, 2020

6
Abranches D.O.,Martins R.O.,Silva L.P.,Martins M.A.R.,Pinho S.P.,Coutinho J.A.P.
Liquefying Compounds by Forming Deep Eutectic Solvents: A Case Study for Organic Acids and Alcohols
Journal of Physical Chemistry B, 124, 4174-4184, 2020

7
Soares B.P.,Abranches D.O.,Sintra T.E.,Leal-Duaso A.,García J.I.,Pires E.,Shimizu S.,Pinho S.P.,Coutinho J.A.P.
Glycerol Ethers as Hydrotropes and Their Use to Enhance the Solubility of Phenolic Acids in Water
ACS Sustainable Chemistry and Engineering, 8, 5742-5749, 2020

8
Vilas-Boas S.,Abranches D.,Crespo E.,Ferreira O.,Coutinho J.,Pinho S.
Experimental solubility and density studies on aqueous solutions of quaternary ammonium halides, and thermodynamic modelling for melting enthalpy estimations
Journal of Molecular Liquids, 300, , 2020

9
Schreiner T.B.,Santamaria-Echart A.,Ribeiro A.,Peres A.M.,Dias M.M.,Pinho S.P.,Barreiro M.F.
Formulation and optimization of nanoemulsions using the natural surfactant saponin from Quillaja bark
Molecules, 25, , 2020

10
Vilas-Boas S.M.,Teixeira G.,Rosini S.,Martins M.A.R.,Gaschi P.S.,Coutinho J.A.P.,Ferreira O.,Pinho S.P.
Ionic liquids as entrainers for terpenes fractionation and other relevant separation problems
Journal of Molecular Liquids, , 2020

11
Vilas-Boas S.M.,Pokorný V.,Štejfa V.,Ferreira O.,Pinho S.P.,Růžička K.,Fulem M.
Vapor pressure and thermophysical properties of eugenol and (+)-carvone
Fluid Phase Equilibria, 499, , 2019

12
Mirarabrazi M.,Martins M.A.R.,Pinho S.P.,Coutinho J.A.P.,Robelin C.
Solid-Liquid Equilibria for Hexafluorophosphate-Based Ionic Liquid Quaternary Mixtures and Their Corresponding Subsystems
Journal of Physical Chemistry B, 123, 8954-8969, 2019

13
Martins M.,Silva L.,Schaeffer N.,Abranches D.,Maximo G.,Pinho S.,Coutinho J.
Greener Terpene-Terpene Eutectic Mixtures as Hydrophobic Solvents
ACS Sustainable Chemistry and Engineering, 7, 17414-17423, 2019

14
15
Abranches D.O.,Schaeffer N.,Silva L.P.,Martins M.A.R.,Pinho S.P.,Coutinho J.A.P.
The role of charge transfer in the formation of type i deep eutectic solvent-analogous ionic liquid mixtures
Molecules, 24, , 2019

16
Abranches D.,Larriba M.,Silva L.,Melle-Franco M.,Palomar J.,Pinho S.,Coutinho J.
Using COSMO-RS to design choline chloride pharmaceutical eutectic solvents
Fluid Phase Equilibria, 497, 71-78, 2019

17
Vilas-Boas S.M.,Vieira V.,Brandão P.,Alves R.S.,Coutinho J.A.P.,Pinho S.P.,Ferreira O.
Solvent and temperature effects on the solubility of syringic, vanillic or veratric acids: Experimental, modeling and solid phase studies
Journal of Molecular Liquids, 289, , 2019

18
Abranches D.,Silva L.,Martins M.,Fernandez L.,Pinho S.,Coutinho J.
Can cholinium chloride form eutectic solvents with organic chloride-based salts?
Fluid Phase Equilibria, 493, 120-126, 2019

19
Martins M.,Pinho S.,Coutinho J.
Insights into the Nature of Eutectic and Deep Eutectic Mixtures
Journal of Solution Chemistry, 48, 962-982, 2019

20
Kurnia K.A.,Fernandes A.M.,Pinho S.P.,Coutinho J.A.P.
Ion speciation: A key for the understanding of the solution properties of ionic liquid mixtures
Physical Chemistry Chemical Physics, 21, 21626-21632, 2019

21
Abranches D.O.,Martins M.A.R.,Silva L.P.,Schaeffer N.,Pinho S.P.,Coutinho J.A.P.
Phenolic hydrogen bond donors in the formation of non-ionic deep eutectic solvents: The quest for type v des
Chemical Communications, 55, 10253-10256, 2019

22
Silva L.P.,Araújo C.F.,Abranches D.O.,Melle-Franco M.,Martins M.A.R.,Nolasco M.M.,Ribeiro-Claro P.J.A.,Pinho S.P.,Coutinho J.A.P.
What a difference a methyl group makes-probing choline-urea molecular interactions through urea structure modification
Physical Chemistry Chemical Physics, 21, 18278-18289, 2019

23
Martins M.A.R.,Carvalho P.J.,Alves D.,Dariva C.,Costa M.C.,Ferreira R.A.S.,André P.S.,Morgado P.,Pinho S.P.,Filipe E.J.M.,Coutinho J.A.P.
Surface crystallization of ionic liquid crystals
Physical Chemistry Chemical Physics, 21, 17792-17800, 2019

24
Vilas-Boas S.M.,Brandão P.,Martins M.A.R.,Silva L.P.,Schreiner T.B.,Fernandes L.,Ferreira O.,Pinho S.P.
Solubility and solid phase studies of isomeric phenolic acids in pure solvents
Journal of Molecular Liquids, 272, 1048-1057, 2018

25
Chelouche S.,Trache D.,Pinho S.,Khimeche K.,Mezroua A.,Benziane M.
Solid–Liquid Phase Equilibria, Molecular Interaction and Microstructural Studies on (N-(2-ethanol)-p-nitroaniline + N-(2-acetoxyethyl)-p-nitroaniline) Binary Mixtures
International Journal of Thermophysics, 39, , 2018

26
Soares B.,Štejfa V.,Ferreira O.,Pinho S.,Růžička K.,Fulem M.
Vapor pressures and thermophysical properties of selected ethanolamines
Fluid Phase Equilibria, 473, 245-254, 2018

27
Crespo E.,Silva L.,Martins M.,Bülow M.,Ferreira O.,Sadowski G.,Held C.,Pinho S.,Coutinho J.
The Role of Polyfunctionality in the Formation of [Ch]Cl-Carboxylic Acid-Based Deep Eutectic Solvents
Industrial and Engineering Chemistry Research, 57, 11195-11209, 2018

28
Chelouche S.,Trache D.,Neves C.,Pinho S.,Khimeche K.,Benziane M.
Solid + liquid equilibria and molecular structure studies of binary mixtures for nitrate ester's stabilizers: Measurement and modeling
Thermochimica Acta, 666, 197-207, 2018

29
Silva L.,Fernandez L.,Conceiçao J.,Martins M.,Sosa A.,Ortega J.,Pinho S.,Coutinho J.
Design and Characterization of Sugar-Based Deep Eutectic Solvents Using Conductor-like Screening Model for Real Solvents
ACS Sustainable Chemistry and Engineering, 6, 10724-10734, 2018

30
Martins M.,Crespo E.,Pontes P.,Silva L.,Bülow M.,Maximo G.,Batista E.,Held C.,Pinho S.,Coutinho J.
Tunable Hydrophobic Eutectic Solvents Based on Terpenes and Monocarboxylic Acids
ACS Sustainable Chemistry and Engineering, 6, 8836-8846, 2018

31
Peixoto C.,Dias M.,Alves M.,Calhelha R.,Barros L.,Pinho S.,Ferreira I.
Grape pomace as a source of phenolic compounds and diverse bioactive properties
Food Chemistry, 253, 132-138, 2018

32
Arrad M.,Aliyeva M.,Vilas-Boas S.,Kaddami M.,Sippola H.,Taskinen P.,Pinho S.
Water Activity and Freezing Points in Aqueous Solutions of Manganese Nitrate: Experimental and Modeling
Journal of Solution Chemistry, 47, 774-786, 2018

33
Schaeffer N.,Martins M.A.R.,Neves C.M.S.S.,Pinho S.P.,Coutinho J.A.P.
Sustainable hydrophobic terpene-based eutectic solvents for the extraction and separation of metals
Chemical Communications, 54, 8104-8107, 2018

34
Crespo E.,Silva L.,Martins M.,Fernandez L.,Ortega J.,Ferreira O.,Sadowski G.,Held C.,Pinho S.,Coutinho J.
Characterization and Modeling of the Liquid Phase of Deep Eutectic Solvents Based on Fatty Acids/Alcohols and Choline Chloride
Industrial and Engineering Chemistry Research, 56, 12192-12202, 2017

35
Coutinho J.,Pinho S.
Special Issue on Deep Eutectic Solvents: A foreword
Fluid Phase Equilibria, 448, 1, 2017

36
Fernandez L.,Silva L.,Martins M.,Ferreira O.,Ortega J.,Pinho S.,Coutinho J.
Indirect assessment of the fusion properties of choline chloride from solid-liquid equilibria data
Fluid Phase Equilibria, 448, 9-14, 2017

37
Pontes P.V.A.,Crespo E.A.,Martins M.A.R.,Silva L.P.,Neves C.M.S.S.,Maximo G.J.,Hubinger M.D.,Batista E.A.C.,Pinho S.P.,Coutinho J.A.P.,Sadowski G.,Held C.
Measurement and PC-SAFT modeling of solid-liquid equilibrium of deep eutectic solvents of quaternary ammonium chlorides and carboxylic acids
Fluid Phase Equilibria, 448, 69-80, 2017

38
Martins M.,Carvalho P.,Palma A.,Domańska U.,Coutinho J.,Pinho S.
Selecting Critical Properties of Terpenes and Terpenoids through Group-Contribution Methods and Equations of State
Industrial and Engineering Chemistry Research, 56, 9895-9905, 2017

39
Martins M.,Silva L.,Ferreira O.,Schröder B.,Coutinho J.,Pinho S.
Terpenes solubility in water and their environmental distribution
Journal of Molecular Liquids, 241, 996-1002, 2017

40
Muhammad F.,Oliveira M.,Pignat P.,Jaubert J.,Pinho S.,Coniglio L.
Phase equilibrium data and modeling of ethylic biodiesel, with application to a non-edible vegetable oil
Fuel, 203, 633-641, 2017

41
Schröder B.,Martins M.A.R.,Coutinho J.A.P.,Pinho S.P.
Aqueous solubilities of five N-(diethylaminothiocarbonyl)benzimido derivatives at T = 298.15 K
Chemosphere, 160, 45-53, 2016

42
Souza M.,Pinho S.,Guimarães P.,Vianna R.
Selection of optimal operating conditions based on minimum energy consumption for an acrylonitrile recovery unit
Separation Science and Technology (Philadelphia), 51, 1830-1839, 2016

43
44
Martins M.,Domańska U.,Schröder B.,Coutinho J.,Pinho S.
Selection of Ionic Liquids to be Used as Separation Agents for Terpenes and Terpenoids
ACS Sustainable Chemistry and Engineering, 4, 548-556, 2016

45
Teles A.,Dinis T.,Capela E.,Santos L.,Pinho S.,Freire M.,Coutinho J.
Solubility and solvation of monosaccharides in ionic liquids
Physical Chemistry Chemical Physics, 18, 19722-19730, 2016

46
Batista M.,Passos H.,Henriques B.,Maginn E.,Pinho S.,Freire M.,Gomes J.,Coutinho J.
Why are some cyano-based ionic liquids better glucose solvents than water?
Physical Chemistry Chemical Physics, 18, 18958-18970, 2016

47
Martins M.,Coutinho J.,Pinho S.,Domańska U.
Measurements of activity coefficients at infinite dilution of organic solutes and water on polar imidazolium-based ionic liquids
Journal of Chemical Thermodynamics, 91, 194-203, 2015

48
Casimiro F.,Constantino D.,Pereira C.,Ferreira O.,Rodrigues A.,Pinho S.
Vapor-Liquid Equilibrium of Binary Mixtures Containing Isopropyl Acetate and Alkanols at 101.32 kPa
Journal of Chemical and Engineering Data, 60, 3181-3186, 2015

49
50
Martins M.,Neves C.,Kurnia K.,Carvalho P.,Rocha M.,Santos L.,Pinho S.,Freire M.
Densities, viscosities and derived thermophysical properties of water-saturated imidazolium-based ionic liquids
Fluid Phase Equilibria, 407, 188-196, 2015

51
Batista M.,Kurnia K.,Pinho S.,Gomes J.,Coutinho J.
Computational and experimental study of the behavior of cyano-based ionic liquids in aqueous solution
Journal of Physical Chemistry B, 119, 1567-1578, 2015

52
Tomé L.I.N.,Sousa C.S.R.,Gomes J.R.B.,Ferreira O.,Coutinho J.A.P.,Pinho S.P.
Understanding the cation specific effects on the aqueous solubility of amino acids: From mono to polyvalent cations
RSC Advances, 5, 15024-15034, 2015

53
Martins M.,Neves C.,Kurnia K.,Santos L.,Freire M.,Pinho S.,Coutinho J.
Analysis of the isomerism effect on the mutual solubilities of bis(trifluoromethylsulfonyl)imide-based ionic liquids with water
Fluid Phase Equilibria, 381, 28-35, 2014

54
Khan I.,Taha M.,Ribeiro-Claro P.,Pinho S.,Coutinho J.
Effect of the cation on the interactions between alkyl methyl imidazolium chloride ionic liquids and water
Journal of Physical Chemistry B, 118, 10503-10514, 2014

55
Martins M.,Neves C.,Kurnia K.,Luís A.,Santos L.,Freire M.,Pinho S.,Coutinho J.
Impact of the cation symmetry on the mutual solubilities between water and imidazolium-based ionic liquids
Fluid Phase Equilibria, 375, 161-167, 2014

56
57
Vilarinho M.,Fernandes I.,Pinho S.
Water activity in aqueous amino acid solutions containing ammonium sulfate at 298.2 K
Journal of Chemical and Engineering Data, 59, 1802-1807, 2014

58
Khan I.,Kurnia K.,Mutelet F.,Pinho S.,Coutinho J.
Probing the interactions between ionic liquids and water: Experimental and quantum chemical approach
Journal of Physical Chemistry B, 118, 1848-1860, 2014

59
Mota P.,Ferreira O.,Hnědkovský L.,Pinho S.,Cibulka I.
Partial molar volumes of l-serine and l-threonine in aqueous ammonium sulfate solutions at (278.15, 288.15, 298.15, and 308.15) k
Journal of Solution Chemistry, 43, 283-297, 2014

60
Khan I.,Kurnia K.,Sintra T.,Saraiva J.,Pinho S.,Coutinho J.
Assessing the activity coefficients of water in cholinium-based ionic liquids: Experimental measurements and COSMO-RS modeling
Fluid Phase Equilibria, 361, 16-22, 2014

61
Kurnia K.A.,Pinho S.P.,Coutinho J.A.P.
Designing ionic liquids for absorptive cooling
Green Chemistry, 16, 3741-3745, 2014

62
Martins M.,Ferreira O.,Hnědkovský L.,Cibulka I.,Pinho S.
Partial molar volumes of glycine and dl-alanine in aqueous ammonium sulfate solutions at 278.15, 288.15, 298.15 and 308.15 K
Journal of Solution Chemistry, 43, 972-988, 2014

63
Pereira A.,Ferreira O.,Pinho S.,Fernandes E.
Multilocal Programming and Applications
Intelligent Systems Reference Library, 38, 157-186, 2013

64
Ferreira O.,Schröder B.,Pinho S.
Solubility of hesperetin in mixed solvents
Journal of Chemical and Engineering Data, 58, 2616-2621, 2013

65
Constantino D.,Pereira C.,Pinho S.,Silva V.,Rodrigues A.
Isobaric vapor-liquid equilibrium data for binary system of glycerol ethyl acetal and acetonitrile at 60.0 kPa and 97.8 kPa
Journal of Chemical and Engineering Data, 58, 1717-1723, 2013

66
Tomé L.,Pinho S.,Jorge M.,Gomes J.,Coutinho J.
Salting-in with a salting-out agent: Explaining the cation specific effects on the aqueous solubility of amino acids
Journal of Physical Chemistry B, 117, 6116-6128, 2013

67
Mota F.,Queimada A.,Andreatta A.,Pinho S.,Macedo E.
Calculation of drug-like molecules solubility using predictive activity coefficient models
Fluid Phase Equilibria, 322-323, 48-55, 2012

68
Ferreira O.,Pinho S.
Solubility of flavonoids in pure solvents
Industrial and Engineering Chemistry Research, 51, 6586-6590, 2012

69
Mota F.,Queimada A.,Pinho S.,Macedo E.
Solubility of drug-like molecules in pure organic solvents with the CPA EoS
Fluid Phase Equilibria, 303, 62-70, 2011

70
Rodrigues V.,Pereira A.,Ferreira O.,Pinho S.
Liquid phase stability via global optimization
AIP Conference Proceedings, 1281, 991-994, 2010

71
Mota F.,Queimada A.,Pinho S.,Macedo E.
Water solubility of drug-like molecules with the cubic-plus-association equation of state
Fluid Phase Equilibria, 298, 75-82, 2010

72
Pereira C.,Silva V.,Pinho S.,Rodrigues A.
Batch and continuous studies for ethyl lactate synthesis in a pervaporation membrane reactor
Journal of Membrane Science, 361, 43-55, 2010

73
Mota F.,Carneiro A.,Queimada A.,Pinho S.,Macedo E.
Temperature and solvent effects in the solubility of some pharmaceutical compounds: Measurements and modeling
European Journal of Pharmaceutical Sciences, 37, 499-507, 2009

74
Ferreira L.,Breil M.,Pinho S.,Macedo E.,Mollerup J.
Thermodynamic modeling of several aqueous alkanol solutions containing amino acids with the perturbed-chain statistical associated fluid theory equation of state
Industrial and Engineering Chemistry Research, 48, 5498-5505, 2009

75
76
António J.,Mota F.,Pinho S.,Macedo E.
Solubilities of biologically active phenolic compounds: Measurements and modeling
Journal of Physical Chemistry B, 113, 3469-3476, 2009

77
Ferreira L.,Macedo E.,Pinho S.
The effect of ammonium sulfate on the solubility of amino acids in water at (298.15 and 323.15) K
Journal of Chemical Thermodynamics, 41, 193-196, 2009

78
Ferreira L.,Pinho S.,Macedo E.
Solubility of l-serine, l-threonine and l-isoleucine in aqueous aliphatic alcohol solutions
Fluid Phase Equilibria, 270, 1-9, 2008

79
Mota F.,Queimada A.,Pinho S.,Macedo E.
Aqueous solubility of some natural phenolic compounds
Industrial and Engineering Chemistry Research, 47, 5182-5189, 2008

80
Pereira C.,Pinho S.,Silva V.,Rodrigues A.
Thermodynamic equilibrium and reaction kinetics for the esterification of lactic acid with ethanol catalyzed by acid ion-exchange resin
Industrial and Engineering Chemistry Research, 47, 1453-1463, 2008

81
Pinho S.
Water activity in aqueous amino acid solutions, with and without KCl, at 298.15 K
Journal of Chemical and Engineering Data, 53, 180-184, 2008

82
Ferreira L.A.,Macedo E.A.,Pinho S.P.
KCl effect on the solubility of five different amino acids in water
Fluid Phase Equilibria, 255, 131-137, 2007

83
Ferreira L.,Macedo E.,Pinho S.
Effect of KCl and Na2so4 on the solubility of glycine and DL-alanine in water at 298.15 K
Industrial and Engineering Chemistry Research, 44, 8892-8898, 2005

84
Pinho S.,Macedo E.
Solubility of NaCl, NaBr, and KCl in water, methanol, ethanol, and their mixed solvents
Journal of Chemical and Engineering Data, 50, 29-32, 2005

85
Pinho S.,Macedo E.
Teaching electrolyte thermodynamics
Chemical Engineering Education, 38, 26-30, 2004

86
Ferreira L.,Macedo E.,Pinho S.
Solubility of amino acids and diglycine in aqueous-alkanol solutions
Chemical Engineering Science, 59, 3117-3124, 2004

87
Xu X.,Pinho S.P.,Macedo E.A.
Activity coefficient and solubility of amino acids in water by the modified Wilson model
Industrial and Engineering Chemistry Research, 43, 3200-3204, 2004

88
89
Pinho S.P.,Macedo E.A.
Representation of salt solubility in mixed solvents: A comparison of thermodynamic models
Fluid Phase Equilibria, 116, 209-216, 1996

90
Pinho S.,Silva C.,Macedo E.
Solubility of Amino Acids: A Group-Contribution Model Involving Phase and Chemical Equilibria
Industrial and Engineering Chemistry Research, 33, 1341-1347, 1994

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